Browsing by Author "Pinho, P.G."
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- Aspects concerning the acoustical performance of school buildings in PortugalPublication . Pinho, P.G.; Pinto, M.; Almeida, Ricardo; Lopes, S.M.; Lemos, L.T.Acoustic measurements were performed in eight schools of different levels of education (from kindergarten to college) located in Viseu – Portugal. The acoustic evaluation was made in order to analyze the most common problems that may condition the acoustic environment inside school building. The acoustics evaluation of school buildings was made by the measurement of: reverberation time in classrooms; sound insulation between classrooms and between classrooms and corridors; impact sound insulation of floors and airborne sound insulation of façade. The sound insulation of façade was made with all elements closed and with natural ventilation conditions (banners or windows tilt mode). It was found that most of the studied cases revealed disabled constructive aspects in relation to the acoustic requirements of school buildings compromising the quality of education.
- Evaluation of isoprene degradation in the detailed tropospheric chemical mechanism, MCM v3, using environmental chamber dataPublication . Pinho, P.G.; Pio, C.A.; Jenkin, M.E.The isoprene degradation mechanism included in version 3 of the Master Chemical Mechanism (MCM v3) has been evaluated and refined, using the Statewide Air Pollution Research Center (SAPRC) environmental chamber datasets on the photo-oxidation of isoprene and its degradation products, methacrolein (MACR) and methylvinyl ketone (MVK). Prior to this, the MCM v3 butane degradation chemistry was also evaluated using chamber data on the photo-oxidation of butane, and its degradation products, methylethyl ketone (MEK), acetaldehyde (CH3CHO) and formaldehyde (HCHO), in conjunction with an initial evaluation of the chamber-dependent auxiliary mechanisms for the series of relevant chambers. The MCM v3 mechanisms for both isoprene and butane generally performed well and were found to provide an acceptable reaction framework for describing the NOx-photo-oxidation experiments on the above systems, although a number of parameter modifications and refinements were identified which resulted in an improved performance. All these relate to the magnitude of sources of free radicals from organic chemical process, such as carbonyl photolysis rates and the yields of radicals from the reactions of O3 with unsaturated oxygenates, and specific recommendations are made for refinements. In addition to this, it was necessary to include a representation of the reactions of O(3P) with isoprene, MACR and MVK (which were not previously treated in MCM v3), and conclusions are drawn concerning the required extent of free radical formation from these reactions. Throughout the study, the performance of MCM v3 was also compared with that of the SAPRC-99 mechanism, which was developed and optimized in conjunction with the chamber datasets.