ESTGV - DI - Artigo em revista científica, indexada ao WoS/Scopus
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Browsing ESTGV - DI - Artigo em revista científica, indexada ao WoS/Scopus by Subject "agroindustrial residues"
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- Olive Tree (Olea europaea) Pruning: Chemical Composition and Valorization of Wastes Through LiquefactionPublication . Domingos, idalina; Domingos Ferreira, Miguel; Ferreira, José; Esteves, Bruno; MDPIOlive tree branches (OB) and leaves (OL) from the Viseu region (Portugal) were studied for their chemical composition and liquefaction behavior using polyalcohols. Chemical analysis revealed that OL contained higher ash content (4.08%) and extractives, indicating more bioactive compounds, while OB had greater α-cellulose (30.47%) and hemicellulose (27.88%). Lignin content was higher in OL (21.64%) than OB (16.40%). Liquefaction experiments showed that increasing the temperature from 140 ◦C to 180 ◦C improved conversion, with OB showing a larger increase (52.5% to 80.9%) compared to OL (66% to 72%). OB reached peak conversion faster, and the optimal particle size for OB was 40–60 mesh, while OL performed better at finer sizes. OL benefited more from higher solvent ratios, whereas OB achieved high conversion with less solvent. FTIR analysis confirmed that acid-catalyzed liquefaction breaks down lignocellulosic structures, depolymerizes cellulose and hemicellulose, and modifies lignin, forming hydroxyl, aliphatic, and carbonyl groups. These changes reflect progressive biomass degradation and the incorporation of polyalcohol components, converting solid biomass into a reactive, polyol-rich liquid. The study highlights the distinct chemical and processing characteristics of olive branches and leaves, informing their potential industrial applications.
