Browsing by Author "Fangueiro, David"
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- Evaluation of a Tomato Waste Biofilter for the Retention of Gaseous Losses from Pig Slurry Hygienization by pH ModificationPublication . Pereira, José L.S.; Perdigão, Adelaide; Fangueiro, DavidThe use of pig slurry as organic fertilizer in intensive horticulture could be possible after hygienization to avoid contamination of products. This research aimed to evaluate a mixture of a tomato waste and rice husk as biofilter media to reduce NH3, N2O, CO2, and CH4 losses from a simple and low-cost solution for slurry hygienization by pH modification. The experiment was made in a system of laboratory scale biofilters connected to jars filled with raw slurry as control and three treatment methods: acidified slurry, alkalinized slurry, and neutralized slurry. The gas concentrations were measured for 35 days, and the composition of slurries and biofilters were determined. The results of this study showed that the mixture of biofiltering media, composed of tomato waste and rice husk, has the potential to retain NH3 and greenhouse gases (GHG) from a simple and low-cost solution for slurry hygienization by pH modification. Compared to the treatment raw slurry biofilter, the treatment neutralized slurry biofilter, subjected to a combined treatment by alkalinization/neutralization, retained 19% NH3, 4% CO2, and 83% CH4 losses and had no impact on N2O and global warming potential. Thus, the use of tomato waste biofilter during alkalinization did not increase the loss of NH3 and reduced GHG compared to raw slurry, avoiding the subsequent neutralization of slurry for environmental reasons, and could be used as an organic fertilizer in horticulture. However, using the combined alkalinization/neutralization treatment will improve the fertilizer value of the slurry by adjusting the pH from 9.5 to 7.5.
- Evaluation of Tomato-Based Packing Material for Retention of Ammonia, Nitrous Oxide, Carbon Dioxide and Methane in Gas Phase Biofilters: A Laboratory StudyPublication . Pereira, José L.S.; Perdigão, Adelaide; Marques, Francisco; Coelho, Catarina; Mota, Mariana; Fangueiro, DavidBiofilters are an effective air pollution control technology to break down gaseous contaminants and produce innocuous end products. This laboratory study aimed to evaluate a biofilter media, mainly composed by tomato waste, as packing material to reduce NH3, N2O, CO2 and CH4 losses from stored pig slurry. Three mixtures of packing materials, with and without oxalic acid, were arranged in treatments, namely: mixture of tomato waste, pine bark and agricultural compost; mixture of tomato waste and rice husk; tomato waste only. A control treatment (no biofilter) was also included. The experiments were conducted using a system of laboratory scale biofilters connected to jars filled with pig slurry and under a constant airflow rate. The gas concentrations were measured for 14 days and the physicochemical of the packing materials were assessed. Results showed that biofilter media mixtures had a potential for NH3 retention ranging from 51 to 77% and the addition of oxalic acid to these biofilters increased NH3 retention to 72–79%. Additionally, the biofilter media mixtures with and without oxalic acid showed a potential retention for CH4 (29–69%) but not for N2O, yet with no impact on the global warming potential. It can be concluded that tomato based biofilters had the potential to reduce gaseous emissions from slurry.
- Impact of pig-slurry treatment and application techniques on ammonia and greenhouse gas emissions in a Mediterranean forage system.Publication . Carneiro, João; Pereira, José Luís; Surgy, Sónia; Soares, Diana; Monteiro, José; Trindade, Henrique; Coutinho, João; Fangueiro, David
- Mitigating Ammonia and Greenhouse Gas Emissions from Stored Pig Slurry Using Chemical Additives and BiocharsPublication . Pereira, José L.S.; Perdigão, Adelaide; Marques, Francisco; Ferreira Wessel, Dulcineia; Trindade, Henrique; Fangueiro, DavidSlurry storage is a significant source of NH3 and greenhouse gas (GHG) emissions. The aim of this laboratory study was to assess the effects of different chemical additives and biochars on the emissions of NH3, N2O, CO2, and CH4 during the short-term storage of pig slurry. The experiment was performed using Kilner jars filled with raw slurry as control and six treatment additives (5% w/w): acidified slurry, alkalinized slurry, neutralized slurry, agroforestry biochar, cardoon biochar, and elderberry biochar. The gas emissions were measured for 30 days, and the composition of the slurries was determined. During short-term storage, the results of this laboratory study indicated that the NH3 emissions were reduced by 58% by acidification and by 20% by the biochars (Agroforestry, Cardoon, and Elderberry treatments), while neutralization reduced this loss by only 12%. Nitrous oxide emissions were not reduced by the chemical additives (Acidified, Alkalinized, and Neutralized treatments), while this loss was increased by 12% by the biochars. Carbon dioxide, CH4, and global warming potential emissions were not affected by the chemical additives and biochars. Furthermore, the absence of differences between the biochars may be related to their similar composition. Regarding the influence of the studied additives on NH3 losses, it can be concluded that acidification was the best mitigation measure and the biochars were quite similar due to their composition. Furthermore, neutralization had the advantage of sanitizing the slurry, but only had a mild impact on NH3 preservation.
- Soil application of acidified slurry as alternative to raw cattle-slurry injection to minimise gaseous emissions in Mediteranean conditionsPublication . Fangueiro, David; Pereira, José Luís; Surgy, Sónia; Vasconcelos, E.; Coutinho, João
- Surface application of acidified cattle slurry compared to slurry injection: Impact on NH 3 , N 2 O, CO 2 and CH 4 emissions and crop uptakePublication . Fangueiro, David; Pereira, José Luís; Macedo, Sofia; Trindade, Henrique; Vasconcelos, Ernesto; Coutinho, JoãoIntensive cattle production has a severe environmental impact due, partly, to ammonia (NH3) and greenhouse gas emissions resulting from handling of the large amounts of slurry (liquid manure) produced. The present study aimed to compare, in terms of NH3, N2O, CH4 and CO2 emissions and crop yield, slurry injection in soil (reference technique) and a combined approach of slurry (S) treatment (by separation and/or acidification) followed by surface application. A pot experiment was performed over 67 days with an oat forage crop amended with S or the separated liquid fraction (LF), with and without acidification to pH 5.5. Injection of S was compared with surface application of treated S followed or not by soil incorporation. Soil injection reduced NH3 emissions to insignificant levels and did not increase N2O emissions, while maintaining oat yields similar to those for the surface application of S. Surface application of acidified S or acidified LF led to NH3 emissions < 7% of applied NH4+-N, with no increase of N2O emissions relative to surface application of S. Furthermore, a stronger decrease of N losses can be achieved by surface application of acidified S followed by soil incorporation. However, surface application of LF without incorporation led to significant NH3 emissions and therefore is not recommended. Significantly lower (p < 0.05) CH4 emissions were observed with application of acidified slurry and LF, relative to the respective non-acidified treatments. These results show that surface application of acidified slurry is a good alternative to slurry injection when the latter technique cannot be used.
- The Implications of Animal Manure Management on Ammonia and Greenhouse Gas EmissionsPublication . Fangueiro, David; Merino, Pilar; Pantelopoulos, Athanasios; L.S. Pereira, José; Amon, Barbara; Chadwick, DavidHigh livestock densities and the subsequent generation of large quantities of manure, in some areas of the world, generate hotspots of increased environmental risks through ammonia (NH3) and greenhouse gas (methane, CH4; nitrous oxide, N2O) emissions. Livestock production is therefore facing increased pressures from society to comply with environmental legislation, so that systems are managed in a sustainable and environmentally friendly manner. A key solution to minimize or avoid environmental and health concerns associated with manure is to ensure appropriate feeding strategies as well as manure management techniques through the entire manure management chain from animal housing, storage of manure, treatment operations and finally application to soil. An integrated framework is needed to allow practical, cost-effective on-farm strategies to be selected, which will reduce losses and improve resource use efficiencies. In this chapter, we first analyse the contribution of manure management to NH3 and GHG emissions with focus on bovine, pig and poultry manure. We then describe different mitigation options for reducing gaseous emissions along the manure management chain in terms of their efficiency to decrease NH3 and GHG emissions and their applicability. Finally, we present and assess two case studies of integrated manure management strategies to reduce gaseous emissions.