Publicação
Olive Tree (Olea europaea) Pruning Autohydrolysis: FTIR Analysis, and Energy Potential
| dc.contributor.author | Domingos, idalina | |
| dc.contributor.author | Domingos Ferreira, Miguel | |
| dc.contributor.author | Ferreira, José | |
| dc.contributor.author | Esteves, Bruno | |
| dc.date.accessioned | 2026-04-15T08:24:19Z | |
| dc.date.available | 2026-04-15T08:24:19Z | |
| dc.date.issued | 2026-02-11 | en_US |
| dc.date.updated | 2026-04-14T15:01:25Z | |
| dc.description.abstract | Olive trees cultivated in the Viseu region (Portugal) were used in the present work. This study investigates the compositional characteristics and hydrothermal behavior of olive branches (OB) and olive leaves (OL) under autohydrolysis, aiming to assess their potential for biorefinery applications. Chemical analysis revealed that during autohydrolysis (140–180 ◦C, 15–30 min), OL exhibited greater solubilization than OB, consistent with their higher extractive content. Increasing the temperature promoted selective hemicellulose removal and partial cellulose degradation, leading to a relative enrichment of lignin in the solid residues. Nevertheless, the cellulose content of olive branches for 180 ◦C and 30 min hydrolysis increased. Fourier transform infrared spectroscopy confirmed progressive structural rearrangements, including enhanced hydroxyl exposure, carbonyl formation, and lignin condensation, indicating the transformation of the solid phase toward more aromatic and thermally stable structures. Autohydrolysis slightly increased the higher heating value of the solid residues while acid-catalyzed liquefaction markedly increased, exceeding those of both native and technical lignins. These results suggest extensive carbon enrichment and oxygen removal during liquefaction. Overall, autohydrolysis proved effective for hemicellulose solubilization and sugar recovery, while liquefaction favored energy densification and lignin condensation. The distinct behaviors of OB and OL highlight the importance of tailoring processing conditions to each feedstock type. Both materials show strong potential as renewable resources for bioenergy and value-added carbon-based products within an integrated olive biomass biorefinery framework | por |
| dc.description.version | N/A | |
| dc.identifier.doi | 10.3390/resources15020030 | en_US |
| dc.identifier.slug | cv-prod-4953585 | |
| dc.identifier.uri | http://hdl.handle.net/10400.19/9780 | |
| dc.language.iso | N/A | por |
| dc.subject | autohydrolysis | |
| dc.subject | agro-industrial residues | |
| dc.subject | chemical composition | |
| dc.subject | FTIR | |
| dc.subject | olive tree pruning | |
| dc.title | Olive Tree (Olea europaea) Pruning Autohydrolysis: FTIR Analysis, and Energy Potential | en_US |
| dc.type | research article | en_US |
| dspace.entity.type | Publication | |
| oaire.citation.title | Resources | en_US |
| person.familyName | Domingos | |
| person.familyName | Domingos Ferreira | |
| person.familyName | Ferreira | |
| person.familyName | Esteves | |
| person.givenName | idalina | |
| person.givenName | Miguel | |
| person.givenName | José | |
| person.givenName | Bruno | |
| person.identifier | 2119255 | |
| person.identifier.ciencia-id | 7116-E1DE-88E7 | |
| person.identifier.ciencia-id | B81E-BE45-E128 | |
| person.identifier.ciencia-id | 521B-63A7-B248 | |
| person.identifier.orcid | 0000-0002-4308-1563 | |
| person.identifier.orcid | 0009-0006-9290-2686 | |
| person.identifier.orcid | 0000-0001-7596-8065 | |
| person.identifier.orcid | 0000-0001-6660-3128 | |
| person.identifier.rid | C-2173-2012 | |
| person.identifier.scopus-author-id | 24281086400 | |
| person.identifier.scopus-author-id | 18133647300 | |
| person.identifier.scopus-author-id | 57202554441 | |
| rcaap.cv.cienciaid | 521B-63A7-B248 | Bruno Miguel Morais Lemos Esteves | |
| rcaap.rights | openAccess | en_US |
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