Browsing by Author "Sahin, Sirri"
Now showing 1 - 5 of 5
Results Per Page
Sort Options
- Calorific Power Improvement of Wood by Heat Treatment and Its Relation to Chemical CompositionPublication . Domingos, Idalina; Ayata, Umit; Ferreira, José; Cruz-Lopes, Luísa; Sen, Ali; Sahin, Sirri; Esteves, BrunoChemical composition influences the calorific power of wood, mainly due to the calorific power of structural compounds and extractives. Heat treatment changes the chemical composition of treated wood. This work studies the relationship between chemical composition and calorific power improvement by heat treatment. Samples were heat-treated by the ThermoWood process ® for 1 h and 2 h. High heating value (HHV) and chemical composition; lignin, cellulose, hemicelluloses and extractives in dichloromethane, ethanol, and water were determined. The HHV of untreated wood ranged between 18.54–19.92 MJ/kg and increased with heat treatment for all the tested species. A positive linear correlation was found between HHV and Klason lignin (R2 = 0.60). A negative trend was observed for holocellulose, cellulose, and hemicelluloses content against HHV, but with low determination coefficients for linear regression. The best adjust for polysaccharides was found for hemicelluloses content. A positive correlation could be found for dichloromethane extractives (R2 = 0.04). The same was obtained in relation to ethanol extractives with R2 = 0.20. For water and total extractives, no clear positive or negative trends could be achieved. The results showed that the HHV of wood increased with heat treatment and that this increase was mainly due to the increase in lignin content.
- Effect of heat treatment on shore-D hardness of some wood speciesPublication . Esteves, Bruno; Sahin, Sirri; Ayata, Ümit; Domingos, Idalina; Ferreira, José; Gürleyen, LeventHardness is an important wood property for several applications. Typically, it is necessary to use traditional methods, such as a universal test machine, to determine a wood’s hardness value. This work reports the hardness of some wood species before and after heat treatment (ThermoWood method) using the Shore-D hardness method. The Shore- D hardness value of untreated wood ranged between 35.3 for Limba wood and 77.2 for Santos wood. With heat treatment, hardness decreased, and the decrease was greater for samples that underwent harsher treatment (2 h at 212 °C). The decrease of hardness was highest for Sipo wood (14%) and the lowest for Afrormosia wood (2.5%). Analysis of variance tests showed that there was a significant difference between wood species, heat treatment, and the interaction between both variables at the chosen level of significance (P ≤ 0.05). Results showed that Shore-D hardness could be used to measure hardness directly in a production line or in small wood companies without using a universal test machine.
- Effect of Thermal Aging on Colour and Glossiness of U System Varnish-applied Laminated Parquet LayersPublication . Ayata, Umit; Sahin, Sirri; Esteves, Bruno; Gurleyen, LeventChanges are reported in perpendicular and parallel glossiness, lightness (L*), red colour (a*) tone, and yellow colour (b*) tone due to thermal aging in beech (Fagus orientalis Lipsky), maple (Acer pseudoplatanus L.), northern red oak (Quercus rubra L.), American black walnut (Juglans nigra L.), and walnut (Juglans regia L.) wood coated with a UV system commonly used on laminated parquets. Coated samples were exposed to different thermal aging levels (30 °C for 30 days, 60 °C for 60 days, and 90 °C for 90 days). Colour and gloss were determined before and after the thermal aging processes. The L* decreased for all species with the thermal aging decreasing more for more intense processes. Variations of the a* and b* colour parameters depended on the species. The colour parameters changed for temperatures higher than 30 °C. In general, glossiness decreased proportionally to the severity of the thermal aging for all of the species studied.
- Effects of artificial weathering on the surface properties of coated radiata pinePublication . Sahin, Sirri; Esteves, Bruno; Can, Ahmet; Sivrikaya, Hüseyin; Domingos, Idalina; Ferreira, José; Ayata, ÜmitRadiata pine boards were coated with two different methods A and B both beginning with a hydro primer and finishing with a mat oil but method A using an acrylic high gloss coating and method B three layers of an acrylic sealer in between. The samples were subjected to aging processes for 144 h, 288 h, and 432 h by using UV-A 340 nm lamps. The CIE L*a*b* and CIE L*C*H* coordinates were determined (L*, a*, b*, C*, ho *, ΔE*), gloss (perpendicular ( ) and parallel (//) to the grain at 20°, 60°, and 85° angles) and surface adhesion strength via the pull-off method were tested before and after weathering. Results have shown that lightness (L*), decreases with weathering for both varnish applications with a higher decrease for the B coating system. Redness increased for both applications with no significant differences. At the same time there was a yellowing of the samples along the weathering period. Parallel and perpendicular gloss decreased for 20º and 60º angles while it increased for 85º angle. The adhesion strength of method A was higher and its decrease with weathering was smaller than for method B. Both varnish applications have proven to confer some protection against wood discoloration, but method A showed the best results and is therefore the best method to be used by radiata pine.
- The effects of thermal aging on color and glossiness in UV cured coatings applied to sessile oakPublication . Sahin, Sirri; Ayata, Ümit; Esteves, BrunoColor and glossiness are two important aesthetic properties of wood flooring and wood furniture that significantly affect consumers choice. With time the coating deteriorates altering the surface properties. Understanding these changes is important for furniture industry, impacting design choices, material selection, and long-term maintenance. The effects of thermal aging (30 °C for 30 days, 60 °C for 60 days, and 90 °C for 90 days) on color parameters (C*, L*, b*. a*, ho) and glossiness on both perpendicular (⊥) and parallel (║) directions at 20°, 60°, and 85° angles in UV-cured coatings applied on sessile oak were studied. Results show that statistically significant differences were observed in the glossiness values, as well as in C*, b*, a*, L* and ho. As the temperature and duration of the thermal aging process increased, there was a noticeable increase in the values of color parameters b*, a*, and C*, while the values of ho and L* decreased. The characteristics of the surfaces exposed to thermal aging have undergone a complete transformation.