ESTGV - DA - Artigo em revista científica, indexada ao WoS/Scopus
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- Carbon footprint calculator for the Portuguese textile and clothing industry: development, application and validationPublication . C. Duarte; Ferreira, José; Lopes Brás, Isabel Paula; Ferreira Silva, Maria Elisabete
- Sustainable Heat Production for Fossil Fuel Replacement—Life Cycle Assessment for Plant Biomass Renewable Energy SourcesPublication . Lopes Brás, Isabel Paula; Fabriccino, Massimiliano; Ferreira, José; Ferreira Silva, Maria Elisabete; Mignano, VincenzoThis study aims to assess the environmental impact of using wood-based biomass as a high-efficiency fuel alternative to fossil fuels for heat production. To achieve this, the life cycle of biomass transformation, utilization, and disposal was analyzed using the life cycle assessment (LCA) methodology with SimaPro 9.5.0.2 PhD software. The system boundaries included extraction, processing, transportation, combustion, and waste management, following a cradle-to-gate approach. A comparative analysis was conducted between natural gas, the most widely used conventional heating fuel, and two biomass-based fuels: wood pellets and wood chips. The results indicate that biomass utilization reduces greenhouse gas emissions (−19%) and fossil resource depletion (−16%) while providing environmental benefits across all assessed impact categories analyzed, except for land use (+96%). Biomass is also to be preferred for forest waste management, ease of supply, and energy independence. However, critical life cycle phases, such as raw material processing and transportation, were found to contribute significantly to human health and ecosystem well-being. To mitigate these effects, optimizing combustion efficiency, improving supply chain logistics, and promoting sustainable forestry practices are recommended. These findings highlight the potential of biomass as a viable renewable energy source and provide insights into strategies for minimizing its environmental footprint.
- Competitive Adsorption of Metal Ions by Lignocellulosic Materials: A Review of Applications, Mechanisms and Influencing FactorsPublication . Weber Macena, Morgana; Helena Pereira; Gonçalves Oliveira Valente da Cruz-Lopes, Luísa Paula; Lucas Grosche; Esteves, BrunoThe rapid expansion of industrial and agricultural activities in recent years has significantly contributed to water pollution leading to a decline in water quality and the need for effective treatment and reuse strategies. Metal contamination in water bodies poses severe environmental and health risks, making the development of cost-effective and sustainable remediation methods essential. Among the various treatment approaches, biosorption using biological adsorbents has emerged as a promising alternative due to its low cost and high efficiency. However, while the adsorption mechanisms of single metals are well understood, the competitive interactions between multiple metal ions during the sorption process remain less explored. In this review, we analyze the competitive biosorption of metals in multi-metallic wastewater systems. Key factors influencing metal removal, such as pH, contact time, biosorbent dosage, and initial metal concentration, are discussed, along with the intrinsic properties of biosorbents and metal ions that affect sorption efficiency. Additionally, we highlight recent studies on agroforestry byproducts as effective biosorbents for metal removal, showcasing their potential for sustainable water treatment. Heavy metals pose significant risks even at low concentrations, necessitating robust regulations and advanced treatment technologies; biomass byproducts, as cost-effective biosorbents, can be optimized through pre-treatment, activation, pH and temperature control, and particle size reduction, while effectively manage
- Life Cycle Assessment of Green Space Irrigation Using Treated Wastewater: A Case StudyPublication . Santos, Lenise; Brás, Isabel; Ferreira, Miguel; Domingos, Idalina; Ferreira, JoséWater scarcity is a pressing issue that makes it essential to manage this resource efficiently and sustainably. One solution to combat this issue is the use of treated wastewater (TWW) to irrigate green spaces in cities. However, it is crucial to evaluate the environmental impacts associated with this practice. To this end, life cycle assessment (LCA) is the most advanced tool available. The objective of this study was to assess the environmental implications of usingTWWfor lawn irrigation in the city of Viseu. The ReCiPe 2016 method, supported by SimaPro software, was employed for life cycle impact assessment (LCIA). An attributional approach was used, and the system boundaries were expanded to include the non-discharge of TWW into the receiving environment, the avoided consumption of domestic water, and the avoided consumption of chemical fertilizers. The results revealed that using TWW for lawn irrigation is preferable in terms of human health and ecosystem damage but unfavorable in terms of resource damage. When considering the impact of water consumption on human health and terrestrial and aquatic ecosystems, it is recommended to use treated wastewater for lawn irrigation.
- Influence of Different Agro-Food Waste on Ammonia and Greenhouse Gas Emissions during CompostingPublication . Pereira, José; Costa, Telma; Figueiredo, Vítor; Marques, Francisco; Perdigão, Adelaide; Brás, Isabel; Ferreira Silva, Maria Elisabete; Ferreira Wessel, DulcineiaComposting is one of the best organic waste management techniques, with zero waste; however, it generates environmental impacts. The objective of this study was to evaluate the emission of NH3, N2O, CO2, and CH4 from the composting of olive, elderberry, and grape agro-food waste. The experiment was carried out using reactors receiving straw as control and three treatments receiving mixtures of straw and olive, elderberry, or grape wastes. The gas emissions were measured for 150 days, and the composition of the mixtures and composts was determined. The results showed NH3 and CH4 emissions were reduced by 48% and 29% by the Olive and Elderberry treatments, while only NH3 loss was reduced by 24% by the Grape treatment. Nitrous oxide, CO2, and GWP emissions were reduced by 46%, 32%, and 34% by the Olive treatment, while these losses were not reduced by the Elderberry or Grape treatments. It can be concluded olive waste can effectively reduce NH3 and GWP, while elderberry and grape wastes are also effective in reducing NH3, but not GWP. Thus, the addition of agro-food waste appears to be a promising mitigation strategy to reduce gaseous losses from the composting process.
- FTIR Monitoring of Polyurethane Foams Derived from Acid-Liquefied and Base-Liquefied PolyolsPublication . Dulyanska, Yuliya; Cruz-Lopes, Luísa; Esteves, Bruno; Guiné, Raquel; Domingos, IdalinaPolyalcohol liquefaction can be performed by acid or base catalysis, producing polyols with different properties. This study compared the mechanical properties of foams produced using polyols from liquefied Cytisus scoparius obtained by acid and base catalysis and using two different foam catalysts. The differences were monitored using FTIR analysis. Acid-catalyzed liquefaction yielded 95.1%, with the resultant polyol having an OH index of 1081 mg KOH/g, while base catalysis yielded 82.5%, with a similar OH index of 1070 mg KOH/g. Generally, compressive strength with dibutyltin dilaurate (DBTDL) ranged from 16 to 31 kPa (acid-liquefied polyol) and 12 to 21 kPa (base-liquefied polyol), while with stannous octoate (TIN), it ranged from 17 to 42 kPa (acid) and 29 to 68 kPa (base). Increasing water content generally decreased the compressive modulus and strength of the foams. Higher water content led to a higher absorption at 1670 cm−1 in the FTIR spectrum due to the formation of urea. Higher isocyanate indices generally improved compressive strength, but high amounts led to unreacted isocyanate that could be seen by a higher absorption at 2265 cm−1 and 3290 cm−1. DBTL was shown to be the best foam catalyst due to higher trimer conversion seen in the spectra by a higher absorption at 1410 cm−1. Acid- and base-derived polyols lead to different polyurethane foams with different FTIR spectra, particularly with a higher absorption at 1670 cm−1 for foams from acid-derived liquefaction.
- Enhancing Liquefaction Efficiency: Exploring the Impact of Pre-Hydrolysis on Hazelnut Shell (Corylus avellana L.)Publication . Cruz-Lopes, Luísa; Duarte, Joana; Dulyanska, Yuliya; Guiné, Raquel; Esteves, BrunoHazelnut shells (HS), scientifically known as Corylus avellana L. shells, are waste produced by companies that process nuts. The main objective of this study was to find an efficient way to maximize the chemical potential of HS by solubilizing the hemicelluloses, which could then be used to recover sugars and, at the same time, increase the lignin content of this material to produce adhesives or high-strength foams. In order to optimize the pre-hydrolysis process, two different temperatures (160 and 170 °C) and times varying from 15 to 180 min were tested. All the remaining solid materials were then liquefied using polyalcohols with acid catalysis. The chemical composition of hazelnut shells was determined before and after the pre-hydrolysis. All of the process was monitored using Fourier Transform Infrared Spectroscopy with Attenuated Total Reflectance (FTIR-ATR) by determining the spectra of solids and liquids after the pre-hydrolysis and liquefaction steps. The highest solubilization of hazelnut shells was found for 170 °C and 180 min, resulting in a 25.8% solubilization. Chemical analysis after the hydrolysis process showed a gradual increase in the solubilization of hemicelluloses as both the temperature and time of the reactor were increased. Simultaneously, the percentages of α-cellulose and lignin in the material also increased with rises in temperature and duration. FTIR-ATR allowed for the detection of significant spectral changes in the hazelnut shells from their initial state to the solid residue and further into the liquefied phase. This confirmed that pre-hydrolysis was effective in enhancing the chemical composition of the material, making it more suitable for the production of adhesives, polyurethane foams, or in the production of bioplastics and composite materials, combined with other biopolymers or synthetic polymers to enhance the mechanical properties and biodegradability of the resulting materials.
- Valorisation of Forest and Agriculture Residual Biomass—The Application of Life Cycle Assessment to Analyse Composting, Mulching, and Energetic Valorisation StrategiesPublication . Brás, Isabel; Ferreira Silva, Maria Elisabete; Raimondo, Roberta; Saetta, Raffaella; Mignano, Vincenzo; Fabbricino, Massimiliano; Ferreira, JoséThe treatment of agricultural and forest residues (AFRs) has become an important issue nowadays, both to avoid improper management and for their enhancement. In the study area of Viseu (Portugal), the AFRs are taken to a Residual Biomass Collection Centre. These are valorised in a Biomass Power Plant to produce electricity. Two further processes could be implemented to valorise this biomass: mulching and composting. This study aims to understand the best strategy to enhance this type of biomass residual considering their environmental performance. The Life Cycle Assessment (LCA) was applied considering a cradle-to-grave approach. Different processes of all the technologies were analysed, and the data collected enabled a comparison of 11 environmental impact categories. The results show that composting is the best alternative, except for global warming and ozone layer depletion, and energy valorisation has the greatest impact on five of the considered categories. In the three processes, impacts are mainly associated with the production and shredding phases of the residual biomass, rather than the transportation stages, due to the short distances covered. In all cases, the value of the final product generates market consequences in terms of electricity and fertiliser production. In line with the aim of the study, its outcomes may provide scientific support to local decision makers in defining best practices in the management of the AFRs.
- Forest waste composting—operational management, environmental impacts, and applicationPublication . Ferreira Silva, Maria Elisabete; Saetta, Raffaella; Raimondo, Roberta; Costa, José Manuel; Ferreira, José; Brás, IsabelIn Portugal, the number of fres and the size of burnt areas are rising dramatically every year, increasing with improper management of agroforestry wastes (AFRs). This work aims to study the composting of these wastes with minimal operational costs and understand the environmental impact and the compost application on burnt soil. Thus, a study of life cycle assessment (LCA) was carried out based on windrow composting processes, considering the avoided environmental impacts associated with the end-product quality and its application as an organic amendment. Three composting piles were made with AFRs from the Residual Biomass Collection Centre (RBCC) in Bodiosa (Portugal). Sewage sludges (SS) from an urban wastewater treatment plant were used as conditioning agent. One pile with AFRs (MC) and another with AFRs and SS (MCS) were managed according to good composting practices. Another pile with the AFRs was developed without management (NMC), thus with a minimal operational cost. Periodically, it was measured several physical and chemical parameters according to standard methodologies. Eleven environmental impacts of compost production, MC and MCS, were analyzed by a LCA tool, and their efect on the growth of Pinus pinea was evaluated, using peat as reference. Composting evolution was expected for both piles. Final composts, MC and MCS, were similar, complying with organic amendment quality parameters. Compost NMC, with no operational management, showed the highest germination index. Piles MC and MCS showed similar environmental impacts, contributing to a negative impact on global warming, acidifcation, and eutrophication. Greater growth was obtained with application of MCS, followed by MC, and fnally, peat. Composting is a sustainable way to valorize AFRs wastes, producing compost that could restore burnt soils and promote plant growth and circular economy.
- Nanotechnology Applied to Cellulosic MaterialsPublication . Fernandes, Ana; Cruz-Lopes, Luísa; Esteves, Bruno; Evtuguin, DmitryAbstract: In recent years, nanocellulosic materials have attracted special attention because of their performance in different advanced applications, biodegradability, availability, and biocompatibility. Nanocellulosic materials can assume three distinct morphologies, including cellulose nanocrystals (CNC), cellulose nanofibers (CNF), and bacterial cellulose (BC). This review consists of two main parts related to obtaining and applying nanocelluloses in advanced materials. In the first part, the mechanical, chemical, and enzymatic treatments necessary for the production of nanocelluloses are discussed. Among chemical pretreatments, the most common approaches are described, such as acid- and alkali-catalyzed organosolvation, 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO)-mediated oxidation, ammonium persulfate (APS) and sodium persulfate (SPS) oxidative treatments, ozone, extraction with ionic liquids, and acid hydrolysis. As for mechanical/physical treatments, methods reviewed include refining, high-pressure homogenization, microfluidization, grinding, cryogenic crushing, steam blasting, ultrasound, extrusion, aqueous counter collision, and electrospinning. The application of nanocellulose focused, in particular, on triboelectric nanogenerators (TENGs) with CNC, CNF, and BC. With the development of TENGs, an unparalleled revolution is expected; there will be self-powered sensors, wearable and implantable electronic components, and a series of other innovative applications. In the future new era of TENGs, nanocellulose will certainly be a promising material in their constitution.